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Solving enzyme reaction and diffusion

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Hi,
I am trying to solve a reaction diffusion problem. It is time dependent and I am expecting to get at t=0 the concentration of product at point d=0. My initial concentration of product is 0. There is a generation of product Rsp= Vmax as in my system S >>> Km.
I am attaching my problem here. Kindly let me know how this issue can be resolved.
Thanks!

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